Antimicrobial flame and smoke spread retardant molding compounds and components molded from these compounds

ABSTRACT

HVAC and building and construction components are molded from novel compositions that meet the flame spread and smoke index, as well as the molding, safety, strength, and aesthetic requirements for this use. In a further embodiment of the invention, these compounds also help to promote better indoor air quality in that they inhibit the growth of microbial contaminants within and even on the surface of products molded therefrom. These compounds are based on thermoset resin, and more particularly, a polyester resin which preferably can comprise a polypropylene glycol dicyclopentadiene copolymerized with maleic anhydride, a low profile additive and hydroxy ethyl methacrylate monomer with additional additives including an appropriate catalyst package, a mold release agent, a thickening agent, a loading of aluminum hydroxide which is from about 40 to 65% by weight, having a loading of glass fibers of from about 10 to about 25% and preferably containing a silver ion containing antimicrobial agent, such as soluble glass containing silver ions.

CROSS-REFERENCE

This application is a continuation-in-part of U.S. application Ser. No.11/980,275, filed Oct. 30, 2007 entitled “Flame and Smoke SpreadRetardant Molding Compounds and Components Molded from These Compounds”herein fully incorporated by reference.

FIELD OF INVENTION

The field of invention is molding compounds that are flame and smokespread retardant, and which in particular meet the standards of UL 723and comparable tests for other industries. Further these compounds aresuitable to be molded into components such as those used in theconstruction industry. These molded components include, for example,those used in HVAC applications such as housings, drain pans, sidewalls, for air handling systems, and building applications, such as doorskins. A preferable use is in hot air handlers, hot air furnaces andother heating and air conditioning applications (“HVAC”). Thesecompounds are generally liquid thermosetting molding resins typicallycharacterized as sheet molding compositions (“SMC”). They can be used inmolding processes such as compression, transfer, andinjection/compression. Related compounds may also have uses as bulkmolding compositions (“BMC”) and thick molding compositions (“TMC®”). Ina further embodiment, certain antimicrobial agents are added so thatthese compounds have a self preservative effect or anti-microbialcharacteristics so as to affect the quality of air which is in intimatecontact with a surface comprised of the compound.

BACKGROUND OF THE INVENTION

Products molded from the composition of this invention desirably havesufficient resistance to fire, flame and smoke spread; adequate glasstransition temperatures; antimicrobial characteristics; noise,vibration, and harshness and/or sound dampening properties; anddesirable surface characteristics; high and low temperature stability;corrosion and shrink resistance; low odor; and cost. Desirably thecompositions include a thermoset resin matrix, such as a modifiedunsaturated polyester which is preferably the product of a condensationpolymerization between a polyol and a di-acid or anhydride. Thethermoset resin is, for example, a copolymer of a C2-C16 alkylene glycoland C5-C36 cycloalkylene compound co-polymerized with an anhydride ordi-acid. This polymer is subsequently dissolved in a reactive monomersuch as styrene, and optionally a C1-C12 OH functionalized acrylatemonomer, dimer or trimer may be incorporated into the formulation. Thecompound most preferably comprises the reaction product of propyleneglycol, dicyclopentadiene and maleic anhydride which is dissolved in ablend of styrene. The resin system can further include a low profileresin additive in order to control shrinkage and allow the compound tobe molded to specification. The resin system is further blended with awetting agent, an intiator package, a mold release agent (such as zincstearate), and with one or more flame retardant additive specificallyincluding aluminium hydroxide, with a thickening agent such as magnesiumhydroxide and glass fibers and optionally carbon black or other fillers.In a further embodiment, the compound also includes antimicrobial agentssuch as silver ion containing compositions or organic anti-microbialagents, and preferably include the silver ion containing compositions,such as silver in glass, (and preferably soluble glass), silver zeolitesor silver sodium hydrogen zirconium phosphate.

The composition of the present invention is further formulated to meetthe desired molding characteristics; to withstand the operatingtemperatures to which they will be exposed; and to have a predeterminedstrength and a desirable user interface including appearance, and noiseattenuation, and low odor. These products can be molded in complexgeometries for part consolidation while maintaining desirable materialcharacteristics. For example, the products may include mounting bracketsfor motors and thus need to be self-supporting as well as supportingother components over a broad range of temperatures. Moreover, theproduct geometries may include large surface areas, sharp angles,projections, recesses, ribs groves, surface texturing, as well ascurving shapes of varying cross-sectional thicknesses for example forfluid dynamics or sound attenuation. Typically, the compounds will havea glass transition temperature from about 150° C. (302° F.) to about175° C. (347° F.).

The molding compositions in accordance with the invention can be formedinto articles used in the construction industry, and specificallyincluding the HVAC industry. Advantageously, the antimicrobial compoundsof the further embodiment of the invention can be used where indoor airquality is of concern, including, for example, HVAC and refrigerationapplications.

In accordance with the present invention, the molded articles haveconfigurations for improving heating and fabrication efficiency and/oreconomics, including large configurations with flat surfaces and sharpangles or curving lines and further which include integrally moldedfunctional or design elements, such as rims, flanges, bosses, male andfemale mating parts. Current regulation requires that that minimum flameand smoke retardant properties are met when surface areas exceed adefined square footage. Consequently, the present invention enables theuse of molded articles in applications that could formerly only besatisfied through the use of fabricated metal parts. This streamlines,and may eliminate dangerous and costly fabrication steps, such ascutting and welding sheet metal. Moreover, the compositions can beeasily modeled based on computer generated models, opening up newpossibilities in product design and/or application. These articles canbe relatively large and have the mechanical strength, even at elevatedtemperatures (typically the heater in a residential furnace may operateat temperatures around 540° C., i.e. 1000° F.), to be self-supportingand to support other elements such as the blower housing and/or motor.The invention thus also relates to molded heating and air conditioningcabinets, housings or parts thereof that are used in air handlers andhot air furnaces for residential and commercial buildings. Thesecompounds may also have applications for specialty molded products inthe construction industry which require flame and smoke spread retardantcharacteristics and in particular having large surface area and moldeddetail including for example entry door skins. Thus, the molded productsmeet the standards as set forth in UL 723, which relates to fire safetyand in particular to the flame and smoke spread which is used todescribe the surface burning characteristics of building materials.Analogous tests are set forth in ASTM E-84, UBC 8-1 and NFPA 225 whichset standards according to the use of the product. UL 723, Class I setsthe highest standard since it includes the lowest smoke spread criteria.These tests are also referred to as the “Tunnel Test” (or for ASTM E-84,the “Steiner Tunnel Test”), which measures how far and how fast flamesspread across the surface of a test sample and the smoke developed asmeasured by photoelectric cells. FIG. 3 illustrates the test conditions.In this test, a sample of material 24 inches wide and 25 feet long (anda defined thickness which in this instance is illustrated as 3/16 of aninch) is installed as the ceiling of a test chamber 10 and exposed to agas flame 12 at one end. The test chamber includes viewing windows 14and culminates in a smoke exhaust duct 16 that includes a light source18 and a photo electric cell 20 that is used to measure the smokedeveloped during testing. The resulting flame spread rating (FSR) isdetermined visually as the test operator watches the progression offlames down the tunnel and calling off distances which are correlatedover time. The flame spread and smoke ratings are individually expressednumbers on a continuous scale in which inorganic reinforced cement boardis 0 and red oak is 100. Building codes have established three classesof performance based upon flame spread and smoke developed indices,which are used to specify requirements within the code. Classdesignations are A or I with a flame spread index of 0-25 feet; B or IIwith a flame spread index of 26-75; and C or III with a flame spreadindex of 76-200. For most building codes the smoke developed index is0-450 but for UL 723 (which includes return air plenums, for example,)has flame spread and smoke developed index of 25 and 50 or lessrespectively.

Test protocols for antimicrobial activity include ASTM E2180 and JISZ2801 which respectively utilize test samples bearing a gel and liquidinoculum in a dilute growth medium and a minimum salt medium. ASTM G21defines a standard method for determining the resistance of syntheticpolymeric materials to fungi. This test involves placing test materialon a nutrient salt agar plate, spraying the sample with a mixture offungal spores and incubating the sample. In a further embodiment, themolded products of the present invention meet the applicablerequirements set forth in these tests for one or more of the microbialcontaminants, which can include viruses, protozoa, bacteria and prionsand more specifically for example including Escherichia coli NBRC 3972,Staphylococcus. Aureus NBRC 12732; and Aspergillus niger NBRC6352.

BACKGROUND OF THE INVENTION

Traditionally, many components used in the construction or buildingindustry such as cabinets for residential and commercial air handlersand hot air furnaces have been fabricated from sheet metal, and involvea large box-like design that has changed very little over the pastseveral decades. While there are numerous reasons why a molded compositecabinet would present advantages over the traditional metal ones(including a government mandate in regard to SEER rating thatmanufacturers improve the efficiency of air handling equipment), theindustry has not been able to pursue this idea commercially. First,there is significant legislation covering fire and flame spread criteriafor the building and construction industry. For example, manyjurisdictions require compliance with standard classifications such asUnderwriters Laboratory (“UL”) test 723 (also known as 25/50 flamespread/smoke index) when there is more than 10 square feet surface areaof non-metallic material utilized in the air flow stream of airconditioning and furnace products having ignition sources. The use ofthermoset composite drain pans and blower housings approach in most, andin some instances, exceeds 10 square feet of surface area. Thus, thedevelopment of a composite material that complies with UL 723 has longbeen an unrequited goal of the construction and building industry andits suppliers.

In accordance with the present invention, a composite material isprovided that meets this standard (as well as the standards of UBC 8-1,NFPA 225, and ASTM E-84, BS 6853, DIN 5510 and NF F 16-101/102).Moreover, the development of a thermoset composite material thatcomplies with UL 723 provides for significant new products for use infurnace and air conditioning as well as for other construction andtransportation applications which require a similar degree of flameand/or smoke spread retardancy. In a further embodiment, the compositematerial had improved long term stability as it avoids degradation dueto microbial activity and may even provide Indoor Air Quality benefitsas it may also meet the requirements of one or more of JIS (JapanIndustry Standard) Z 2801, ASTM E2180, and ASTM G21.

A second advantage provided by the present invention has to do withsound characteristics. While there are often legislative mandatesrelating to flame and smoke spread for building and constructionapplications, there are generally fewer government restrictions relatingto noise or sound. It is none-the-less a significant advantagecommercially to address these characteristics as the consumer willgenerally select a product with lower noise emissions. As an example, anair handler or furnace cabinet is often a relatively large hollow boxthat can actually act to amplify motor sounds, if not sufficientlydampened for sound transmission. Thus, in addition to the governmentmandated issues relating to fire/flame spread, it is furtheradvantageous if the components help to meet the consumers' demand forquiet home heating and air conditioning. The present invention may alsobe used to help to improve air quality. The thermoset composite of thepresent invention helps to further these goals by presenting improvedsound dampening ability over the prior art sheet metal components.

Molded polymeric components including for example housings or cabinetsor components thereof, present many additional advantages over the priorart metal components. They significantly reduce the potential for injuryduring assembly by eliminating the need for high temperature weldingoperations, and for cutting and bending sheet metal. They greatlyincrease the efficiency of assembly by providing the opportunity forconsolidation of components for example, by providing integrally moldedfunctional elements, such as mating elements and/or mounting flanges.Thus, molded polymeric housings have been in use for a significantperiod of time for blowers for air conditioners, and in particular roomair conditioners. In addition, they have been used for small scaleheating blowers subjected to relatively low temperatures, such as hairdryers. These applications often involve the use of very expensivecompositions, which can be used since the size is small and they are notrequired to meet the flame spread smoke index retardancy previouslydiscussed. Other hot air furnace components, such as the condensate pan,have been made of molded resins for some time.

However, despite the use of molded polymerics for these otherapplications and for housings in window air conditioners for well over30 years, the HVAC industry has failed to capitalize on the manyadvantages that could be realized through the use of large moldedpolymeric components for hot air furnaces, air handlers and airconditioning units. There are several reasons to account for the priorart practice, including the belief that the blower environment is bettersuited for metal, which has proven longevity and noted fire resistance.An additional problem is the lack of understanding in the compoundingindustry of how to achieve sufficient structural reinforcement, such asthrough the use of glass fiber reinforcement, while maintaining properflame and smoke properties for this application. Finally, despite thelong recognized advantages and economic incentives, the prior art hasfailed to produce an acceptable composite material that meets the fire,smoke, and flame spread criteria as set forth in UL 723 Class I and thatis moldable in complex shapes with an acceptable appearance.

The present invention provides the solution to the previously mentionedissues, while also presenting a platform for improved efficiencies inthe HVAC industry. The present invention provides a molded compositecabinet or cabinet components for hot air furnaces, air handlers and/orair conditioning units. This cabinet may include integral moldedfunctional parts, such as mating elements, and mounting flanges. It hasthe desired mechanical properties including tensile and impactproperties at the necessary operating temperature range. It can bemolded into complex configurations and surface characteristics. It doesthis while maintaining quiet and safe operating conditions.

In addition to the regulations relating to the smoke and flamecharacteristics of the present invention, there is pending legislationand political posturing regarding the issue of Indoor Air Quality (IAQ).This debate centers around a growing awareness and concern with “sickbuilding syndrome” in which residential and commercial buildings areconstructed to conserve energy by sealing the building and relying oncentral cooling and heating systems to maintain comfortable livingtemperatures and humidity by re-circulating internal air (andpollutants). Various factors influence the quality of the indoor air,including for example, the supply and quality of the ambient outsideair; contamination of indoor air from building materials, carbonmonoxide, tobacco smoke, fabric furnishings, carpet adhesives, paintfumes and cleaning products, as well as microbial contamination ofventilation systems or building interiors. The present inventionprovides an additional method of achieving compliance with existing orproposed regulations by inhibiting or even reducing microbial growthwithin an HVAC or other construction surface.

SUMMARY OF THE INVENTION

The present invention provides hot air furnace/air handler blowerhousings which are molded from compositions that meet the molding,safety, strength, and aesthetic requirements for this use. Thesecompounds are typically liquid thermoset resins with a specific level offlame retardant and reinforcement additives to achieve the requiredsafety and desired sound dampening, and in a further specificembodiment, the antimicrobial characteristics, for this article withoutsacrificing molding characteristics. Additional additives includeinitiators and molding agents to permit the compositions to be moldedinto the desired shape by a variety of types of molding processes.Optimally, the base resin can include a polyester resin and morespecifically is a thermoset resin matrix such as a modified unsaturatedpolyester which is preferably the product of a condensationpolymerization of a polyol. Most preferably the resin can be thereaction product of polypropylene glycol dicyclopentadiene and maleicanhydride which is subsequently dissolved in styrene. The system canfurther include a saturated polyester low profile additive and hydroxyethyl methacrylate monomer with additional additives including anappropriate catalyst package, a mold release agent, a thickening agent,a loading of aluminum hydroxide which is from about 40 to 65% by weight,and more preferably from about 45 to about 60% by weight, and mostpreferably from about 52 to about 58%, and having a loading of glassfibers of from about 5 to about 40%, and preferably from about 10 toabout 25%.

In particular, the formulations involve the use of a resin matrix withsignificant loadings of flame retardant and glass filler; variousadditional additives, such as initiators, inhibitors, mold-releaseagents, shrink control additives, viscosity agents, flow modifiers,thickeners, styrene, and carbon black or pigments or other desirableadditives, specifically including antimicrobial agents in a furtherembodiment of the invention.

The foregoing improvements in articles molded from these compositionsenable the low cost mass production of cabinets, drain pans, housingsand other components used in hot air furnaces/air handlers, airconditioners, ventilation and refrigeration systems and other HVAC andair handling and air transport surfaces. These improvements furtherallow for the far greater flexibility in component design in order tomeet the mandate of improved unit efficiency, and improved air qualityand also permit the combination of functions in a single article so asto permit greater fabrication efficiency, lower cost and a smaller unitfoot print.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is an illustration of a Thick Molding Compound Machine;

FIG. 2 is an illustration of a Sheet Molding Compound Machine; and

FIG. 3 is an illustration of the test set-up for a Steiner Tunnel Test.

DETAILED DESCRIPTION OF THE INVENTION

The invention relates to composite resins having the required flame,fire and smoke spread characteristics for use in the HVAC industry. In afurther embodiment of the invention, the composite resins furtherinclude antimicrobial agents so as to meet industry standards to inhibitthe growth of one or more microbial contaminants. The invention furtherrelates to components used in air handlers and hot air furnaces and inparticular HVAC or other air quality control components made from thesecomposite resins. These resins can be used in injection moldingprocesses, in transfer molding processes, in compression moldingprocesses, and in injection/compression molding processes to make theair handling components. These processes are cost effective because theyeliminate labor intensive machining and fabrication. The processesfurther have better ability to control shot to shot cross parting linethickness. Further these molding processes enable the production ofcomplex configurations that have integral functional features and thathave significant concentrations of fillers including fiber reinforcementand flame retardants.

One component of the molding resin composition is a cross linkableunsaturated polyester resin that is the reaction production of acondensation polymerization of a polyol including one or more of thefollowing polyols: ethylene glycol, propylene glycol, neopentyl glycol,diethylene glycol, dipropylene glycol, trimethylpentanediol, cyclohexanediol, propoxylated bisphenol A, hydrogenated bisphenol A, and blendsthereof. These polyols are polymerized with an acids or anhydrideincluding one or more of the following as well as dimers and blendsthereof: phthalic anhydride, maleic anhydride, adipic acid, isophthalicacid, orthophthalic acid, terephthalic acid, fumaric acid, glutaricacid, azelaic acid, and endomethylenetetrahydrophthalic anhydride. Theseare optionally cross-linked (during molding) with a low profile additivewhich can include one or more of the following polymethylmethacrylate,polyethylmethacrylate, co-polymers with other acrylates, polystyrene,polystyrene copolymers, polyvinyl acetate, polyethylene, saturatedpolyesters, and shrinkage control agents. The saturated polyesters andshrinkage control agents include vinyl chloride-vinyl acetatecopolymers, polyurethanes, styrene butadiene copolymers,polycaprolactone, and cellulose acetate butyrate. The low profileadditives can be added directly to the formulation or they can beapplied or incorporated onto a carrier material such as a filler. Themolding compound can be reinforced with, for example, fiber glass,aramid fibers, carbon fibers, or mineral reinforcements such as mica. Inaddition nano-fibers and nano-fillers can be added. Other polymermaterials that can be used include bulk (or dough) molding compound,kneading molding compound, an injection molding compound known as ZMC,and thick molding compound.

Desirably the prepolymer has a relatively low molecular weight such asfrom about 200 to about 5000 (weight average) and a glass transitiontemperature from about 150° C. (302° F.) to about 175° C. (347° F.). Thepolyester resins are the condensation product derived from thecondensation of unsaturated polybasic acids and/or anhydrides withpolyols such as dihydroxy or trihydroxy compounds. Desirably, thesepolyester resins are the esterification reaction product of diacids, oranhydrides of diacids, generally having from about 3 to about 12, ormore preferably from about 4 to about 8 carbon atoms, with a polyol or acyclic ether having from about 2 to about 12, or more preferably fromabout 2 to about 6 carbon atoms.

For some applications a vinyl ester can be used in addition to apreviously described polyester or even as the resin. In this case, thevinyl ester resins that can be used are the reaction products of epoxyresins and a monofunctional ethlenically unsaturated carboxylic acid.More specifically, these vinyl ester resins are the reaction product ofan epoxy terminated oligomer, for example, an epoxy functionalizedbisphenol A with an acrylic acid, or methacrylic acid forming acrylicterminal groups on the oligomer. The vinyl esters have predominantlyterminal unsaturation while the unsaturated polyesters havepredominantly internal unsaturation.

Another component of the molding composition is one or more unsaturatedmonomer that is copolymerizable with the resin. Desirably, thiscomponent is capable of dissolving the resin component at roomtemperature. Thus, in one embodiment the resin is dissolved in themonomeric component prior to being combined with the remainingcomponents. Examples of suitable monomers are styrene, alpha-methylstyrene, vinyl toluene, divinyl benzene, diallylphthalate, hydroxy ethylmethacrylate, methyl methacrylate, and mixture of these, with preferredmonomers being styrene, hydroxy ethyl methacrylate, and methylmethacrylate, and most preferably styrene. The ratio of monomer(s) toresin is desirably from about 5:95 to about 50:50 and preferably fromabout 10:90 to about 25:75 by weight.

Another component in the molding composition is fillers. In accordancewith the invention the predominant filler is flame retardant filler. Thepreferred flame retardant filler is a loading of aluminum hydroxide,which is from about 40 to 65% by weight, and more preferably from about45 to about 60% by weight, and most preferably from about 52 to about58%. These loadings can also be expressed as parts per hundred resinwherein the weight of the resin includes the basic resin, any lowprofile additive, and the monomer. These amounts range from about 250 toabout 400 parts per hundred “pph” resin to preferably from about 275 toabout 350 pph, and most preferably from about 300 to about 325 pph. Inaddition reinforcing filler is added in order to impart structuralproperties and sound dampening to the final molded product. A preferredfiller is glass fibers and fibrous reinforcing agents such as cottonglass fibers or graphite microfibers; The fibers may comprise choppedsized glass microfiber rovings at an amount below 25% for sounddampening, and preferably from about 10 to about 25%, and morepreferably from about 15 to about 22%, and most preferably about 18 toabout 24% in particular for the blower housing having a loading of 22%.The fibers are from about ⅛ to about ½ inch for BMC, to about ¼ to about2 inches for SMC, and from about ¼ to about 1 inch for TMC.

An initiator is another component of the molding composition. Theinitiator initiates the copolymerization of the resin and themonomer(s). Initiators include any free radical initiator capable offorming radicals in the correct concentration under the moldingconditions. They may include peroxides, hydroperoxides, redox systems,diazo compounds, persulfates, perbenzoates. The initiators are typicallyused in amounts of about 0.05 to about 5 weight percent, and morepreferably about 0.1 to about 2 weight percent. Alternatively, theseamount can be expressed in parts per hundred parts by weight of resin,i.e. from about 0.5 to about 4.0 phr, preferably from about 0.7 to about3.0 phr, and most preferably from about 0.8 to about 2.25 phr.Alternatively high temperature initiators such as Di-cup, e.g. dicumylperoxide can be used for molding applications where higher initiationtemperatures are desirable. Peroxy Ester and Perketal initiators arepreferred. Inhibitors can also be added to the catalyst package, such astoluhydroquinone and diethylene glycol.

The inclusion of 0.5 to 10 phr, preferably about 1 to 8 phr, of a moldrelease agent, such as Tech-lube HV706, calcium stearate, zinc stearatesuch as NORAC COAD 27D, or the like may also be of advantage toachieving without machining the complex molded part of the presentinvention. Tech-lube HV706 is proprietary composition of fatty acids,glycerides, polymeric resin and phosphate surfactant sold by Tech-nickProducts of New Jersey. A viscosity reducer can be used in combinationwith styrene to maintain the molding properties, and to decrease thecost of the composition.

Another optional component to the improved molding composition is arheological modifier or thickener, which may act to increase themolecular weight such as by chain extension of the resin prepolymer.Suitable modifiers include Group II oxides and hydroxides, such ascalcium or magnesium oxide or hydroxide. These modifiers may act toincrease shear and thus promote flow and glass carry in the compositionduring molding. Fumed silica is an example of an additional substance,which may act mechanically to increase molding viscosity and thereforealso be a suitable rheological modifier either alone or in combinationwith the previously mentioned ingredients. Magnesium oxide is apreferred thickener to achieve suitable molding characteristics for SMC.

Desirably the rheological modifiers are used in an effective amount toenhance molding properties, such as thickening the resin system prior tomolding. Desirable amounts of group II oxides (including group IIhydroxides and mixtures of these compounds) is from about 0.1 to about 1or about 2 weight percent, more desirably from about 0.2 or about 0.3 toabout 0.7 or about 0.8 weight percent. This can also be expressed asfrom about 0.5 to about 4.0 phr, preferably from about 1.0 to about 3.0phr, and most preferably from about 1.5 to about 2.5 phr. Specificpreferred compounds include magnesium oxide, or magnesium hydroxide orcalcium oxide. Examples of suitable magnesium oxide additives are 99%pure magnesium oxide sold under the trade name “Elastomag” from MortonThiokol, Inc. in Danvers, Mass. Other examples include a magnesium oxidedispersion sold under the trade name “PG-9033” by Plasticolors, and amagnesium hydroxide dispersion also sold by Plasticolors under the tradename “PG-91146”. Another suitable magnesium hydroxide is from Barcroft,which is a powdered version. Fumed silica could be used at from about0.5 to about 20 phr, preferably from about 1 to 10 phr.

Other components to the molding composition include flame retardantssuch as aluminum hydroxide for example sold by Albemarle Corporationunder the trade name ON-921, which has a sieve residue of greater than40% at 45 μm or Moldex A120 sold by Huber, with the ON-921 beingpreferred. The preferred flame retardant filler is a loading of aluminumhydroxide which is from about 40 to 65% by weight, and more preferablyfrom about 45 to about 60% by weight, and most preferably from about 52to about 58%.

The composition may also include flexibilizing agents; mold releaseagents; polymerization inhibitors to inhibit premature polymerizationduring storage or the initial stages of molding; viscosity modifierslike fumed silica; and mold lubricant like stearates of calcium, zinc ormagnesium.

In addition, shrink control additives can advantageously be added toimprove the surface characteristics and the dimensional stability of theresulting products. These shrink control additives include “anti-shrink”and “low profile additives” as part of this aspect of the invention.These additives generally include thermoplastics or elastomerics such ashomopolymers of ethylene, styrene, vinyl toluene, alkyl methacrylates,polyethylene ether, polyphenylene oxide and alkyl acrylates. Additionalexamples include copolymers using the foregoing and in addition, vinylchloride, vinyl acetate, acrylonitrile, and butadiene. In particularthese co-polymers would advantageously include copolymers of vinylchloride and vinyl acetate; styrene and acrylonitrile; methylmethacrylate and alkyl esters of acrylic acid; methyl methacrylate andstyrene; methyl methacrylate and acrylamide; and SBS block copolymers.Particularly advantageous additives are thermoplastics, with saturatedpolyesters being preferred among these. These additives are generallyused in the range of 10 to 50 weight percent based on the total weightof the additive and the resin system, i.e. the resin and any monomers.More preferably this range would be 20 to 45 weight percent, with aparticularly preferred range of about 30 to 40 weight percent. Theseadditives are usually added with the resin blending. As necessary thecure system may be adjusted to compensate for the presence of theadditive.

Suitable initiators include Vazo (2,2-azo bisisobutyronitrile) availablefrom Dupont, I & B Industrial and Biochemical Dept, Wilmington Del.,tert-butyl peroxy isopropyl carbonate (Triginox BPIC) available fromDurr Marketing in Pittsburgh, Pa., t-butylperbenzoate (TBPB) availablefrom Durr Marketing, and 1,3 di-t-butyl peroxy-3,5,5trimethylcyclohexane catalyst (Trig 29B75) available from DurrMarketing.

Calcium stearate and zinc stearate sold as COAD 27 by the Norac Company,Incorporated of Azusa, Calif. can be used as mold release agents, as canTech-Lube HV-706, which is a proprietary composition of fatty acids,glycerides, polymeric resin and phosphate surfactant.

In a further embodiment of the invention, the molding compositionsinclude at least a sufficient quantity of an anti-microbial agent toprovide improved product life by inhibiting degradation due to microbialaffect. More preferably, sufficient quantity of an appropriate agent isincluded to provide for improved external benefits, such as improved airquality for molded components for air handling or refrigeration or fortransportation of potable water or food products. Suitable antimicrobialagents include organic and metal containing compositions, such astriclosan, zinc omadine, and various silver containing additives, suchas silver sodium hydrogen zirconium phosphate, silver zeolite, andglass/silver combinations, such as microspheres, nanospheres ornanotubes, and soluble glass and silver ion combinations. In accordancewith the invention, silver ion containing antimicrobials are preferred,and specifically include inorganic silver glass products such as is soldunder the tradename “IONPURE” by Ishizuka Glass Co. LTD., of NagoyaJapan. Other acceptable products include silver ion containing zeoliteand inorganic silver glass sold by CIBhA Corporation under the tradename“IRAGUARD”, by AGiON Technologies under the tradename “AGION”, byMilliken Chemicals under the tradename “ALPHSAN”, by Clariant Chemicalsunder the tradename “A21-60”, by Astoria under the tradename “IPF”.Suitable organic antimicrobial product include Rohm & Haas products soldunder the tradename “VINYZENE” Suitable amounts depend somewhat on thedesired affect and the target microorganism, but generally range from0.0001% to 5%, and more preferably from 0.001% to 3% by weight, and mostpreferably from 0.01 to 2% by weight of the total system. In the eventthat target microbes include those that are harder to eradicate, higherconcentrations of antimicrobials are necessary (such as for the case ofBacillus sp. and Aspergillus niger NBRC6352 for which a 2% solution ofsilver glass has been shown to be 93% effective in accordance with oneof the accepted industry test protocols. Otherwise, for microbesincluding for example, including Escherichia coli NBRC 3972,Staphylococcus. Aureus NBRC 12732 can be controlled at 0.3% of IONPUREin a test sample when tested according to JIS Z 2801. Microbes to becontrolled include for example, gram positive bacteria such asStaphylococcus, Enterococcus, Streptococcus, and Bacillus; gram negativebacteria such as Pseudomonas, Klebsiella, E Coli, and Salmonella; Fungi,such as Aspergillis, Candida, Cladosporium, and Penicillium.

The molding compositions may be formulated and mixed using a variety ofmixing conditions including either continuous or batch and using avariety of known mixing equipment. Specific examples are set forth inthe example section. FIGS. 1 and 2 illustrate SMC and TMC Machines thatreceive glass rovings that are chopped and impregnated with a paste ofthe resin system and compacted between two layers of a carrier film. Thecompositions may be advantageously stored for reasonable times beforemolding. The compositions can be molded by a variety of methodsincluding compression, transfer, and injection molding or combinationsof theses techniques. The compositions can be molded under typicalconditions for these types of molding including at pressures from about400 to about 9000 psi, and preferably from about 2000 to about 3500 psi,and most preferably from about 2500 to about 3000 psi and temperaturesat from about 225 to about 400 degrees Fahrenheit. Dwell times are fromabout 10 seconds to about four minutes. Advantageously, silver glassantimicrobial agents, such as the IONPURE, are added from a masterbatchproduced with from about 5% to about 50%, and more preferably about 10%to about 30% IONPURE in the resin which is diluted in the ultimate resinsystem.

Otherwise conventional injection molding techniques apply as isdiscussed for example in U.S. Pat. No. 6,365,069 B2 incorporated byreference herein. It is preferable to avoid temperature variations atthe mold level. At normal cure rates, the dwell time for injectionmolding is typically around 5 to 600 seconds, or more usually 30 to 300seconds or around one or two minutes. The process can be practiced forsingle or double gate cavity tools, or even for injection/compressionprocesses in which the mold is slightly opened during fill and the moldis shut to compress the shot.

The articles from the composition desirably have tensile strength fromabout 2000 to about 6000 psi as measured in accordance with ASTM testNo. D638 and flexural modulus from about 3000 to about 10,000 psi whentested in accordance with ASTM test no. D790.

Molded products made from the compositions of the present invention areuseful for a variety of applications demanding complex configurations,as well as strength, and corrosion resistance. One particularlyadvantageous product, which can be made by compression molding, is ablower housing. The housing is typically molded in two parts and fittedtogether.

Waiting on results for 300, 350, and 380 pph flame retardant. Gell andflow changed slightly.

EXAMPLES

Resin A is S903 styrene solution of an unsaturated polyester resin basedon propylene glycol and dicyclopentadiene and maleic anhydride sold byAOC.

Resin B is a low profile additive resin formulated for use in SMCapplications sold by Ashland Chemical under the designation Q8000.

Resin C is a styrene solution of an unsaturated polyester resin based onpropylene glycol and maleic anhydride sold by Reichhold Chemicals underthe designation 31-615-20.

Resin D is a styrene solution of an unsaturated polyester resin sold byReichhold Chemicals under the designation 31009.

Resin E is a styrene solution of an unsaturated polyester resin whichalso contains a soluble low profile additive system which is sold by AOCunder the designation S988-500.

Resin F is a styrene solution of an unsaturated polyester resin sold byReichhold Chemicals under the designation 31610.

Monomer A is a hydroxyethyl methacrylate monomer sold by Rohm & Hassunder the designation ROCRYL 400.

Low profile additive A is FN-510, a linear low-density polyethylene fromEquistar Chemicals, L.P. of Houston, Tex.

Low profile additive B is N 700 is a styrene solution of PMMA which is anon-reactive additive for minimizing shrinkage during cure of polyesterresins sold by AOC.

R 100 is a high impact polystyrene from Chevron in styrene solution.These ingredients are added together to comprise the base resin for 100phr.

Flame retardant A is Antiblaze DMMP. A high phosphorus content additiveflame retardant sold by Akzo Nobel under the tradename, FYROL.

Flame retardant B is ON-921 aluminium hydroxide from Hueber, andsimilarly SB 222 and SB 432 are alumina trihydrate flame retardants fromHueber.

Dispersing agent A is BYK-W-996 anionic setting and dispersing additivesold by Dar-Tech.

Initiator A is Trigonox BPIC-C75 Tert-butyl peroxy isopropyl carbonatefrom Durr Marketing in Pittsburgh, Pa.

Initiator B is Trigonox 210P50 an alkylperoxyester (tert-Butylperoxy-2-ethylhexanoate available from Durr Marketing in Pittsburgh, Pa.

Inhibitor A is IN-9073 is Toluhydroquinone in Diethylene Glycol fromPlasticolors.

Inhibitor B is In 91029 is an inhibitor solution of2,6,-di-tert-butyl-p-cresol in vinyl toluene sold by Plasticolors.

Inhibitor C is IN-9139 is a BPQ inhibitor solution from Plasticolors.

Mold release agent A is Zinc stearate COAD 27D from Norac Company.

Colorant A is a grey colorant containing carbon black, titanium dioxide,toner pigments, a saturated polyester resin sold by Ferro-PDI under thedesignation 11-81521.

Thickener A is PG-91146 is a magnesium hydroxide dispersion fromPlasticolors.

Thickener B is AM 9033, a neutral accumag thickener from Plasticolors.

Rheological Additive A is Garamite 1210, a rheological additive forvinyl ester and unsaturated polyester resins from Rockwood Additives.

Glass fibers used is Owens Corning P-973C-AB-113 or 5509 (10-20 micron)continuous strand glass roving with silane sizing

The molding compositions are generally prepared by adding the resin,monomer, initiator, inhibitor, mold release agent, and rheologicalmodifier (if present) to a high shear cowls disperser to form a paste.The paste is then applied to two carrier films to form a sandwich layerwith the glass fibers in the middle. The paste viscosity is in the rangeof 10,000 to 40,000 cps, with the paste temperatures in the range of 38°C. to 49° C. The compound is allowed to thicken or mature, normally 2 to5 days the to reach a viscosity of about 20×10⁶ to about 30×10⁶ cps.FIG. 1 illustrates a TMC® machine which is suitable for use incompounding the material in accordance with the present invention. Inparticular, paste is transferred into a doctor box 104′ along with glassrovings 106′ which are fed through chopper blades 110′ along with thepaste and subsequently sandwiched between two layers of carrier film108′. This is compacted between compaction rollers 112′. FIG. 2illustrates an SMC machine in which paste 102 is transferred into SMCmachine doctor boxes 104 along with glass rovings 106 which are fedthrough chopper blades 110 along with the paste and subsequentlysandwiched between two layers of carrier film 108. This is compactedbetween compaction rollers 112 and monitored with a gamma gauge 114 inorder to produce the desired thickness of product.

After maturing the compound can be molded in a number of various methodscompression molding, injection molding, injection compression molding,and transfer molding. Molding temperatures can vary from 140° C. to 160°C. and molding dwell times can be from 1 to 6 minutes. Molding pressurescan vary from 500 psi to 3000 psi.

Tables 1 through 6 set forth recipes of compositions in accordance withthe present invention which were tested for molding into furnacehousings. Ingredients are listed in parts per hundred of resin (PHR).Tables 7 and 8 set forth recipes of composition in accordance with afurther embodiment of the invention that have antimicrobial propertiesand can be molded into products including for example drain pans and airhandling components.

TABLE 1 Example 1 2 3 4 Resin A (S903) 76.30 76.30 78.40 61.10 Lowprofile additive (R-152) 15.80 33.30 Resin B (Q-8000) 15.80 16.20Monomer A 7.90 5.40 5.60 (ROCRYL 400 [HEMA]) Dispersing agent A 4.204.20 4.30 4.40 (BYK-W-996) Flame retardant A 8.10 5.60 (Antiblaze DMMP)Initiator A (TRIG. BPIC-C75) 1.10 1.10 1.10 1.10 Initiator B(TRIG.21OP50) 0.40 0.40 0.40 0.40 Inhibitor A (IN-9073) 0.20 0.20 0.200.20 Mold release agent A 5.30 5.30 5.40 5.60 (NORAC COAD 27D ZNST)Colorant A (11-81521 [Grey]) 7.90 7.90 8.10 8.30 Flame retardant B(Martinal 289.00 289.00 289.00 302.00 ON-921 ATH Albemarle) Solid glassspheres (3000 CP- 01 SPHERIGLASS) Thickener A (PG-91146) 4.30 5.60Thickener B (AM-9033) 2.63 2.63 Glass fibers (P-973CAB-113) 115.70115.70 118.90 122.20 Total 526.43 526.43 539.80 555.40

TABLE 2 Example 5 6 7 8 Resin A (S903) 59.20 61.10 60.30 Resin C(31-615-20-X) 59.20 Stryene monomer (R-152) Resin B (Q-8000) 32.90 32.9033.30 33.80 Monomer A 7.90 7.90 5.60 5.90 (ROCRYL 400 [HEMA]) Dispersingagent A 4.20 4.20 4.40 4.70 (BYK-W-996) Flame retardant A 5.60 5.90(Antiblaze DMMP) Initiator A (TRIG. BPIC-C75) 1.10 1.10 1.10 1.18Initiator B (TRIG.21OP50) 0.40 0.40 0.40 0.40 Inhibitor A (IN-9073) 0.200.20 0.20 0.20 Mold release agent A 5.30 5.30 5.60 5.90 (NORAC COAD 27DZNST) Colorant A (11-81521 [Grey]) 7.90 7.90 8.30 8.80 Flame retardant B(Martinal 290.00 290.00 302.00 313.00 ON-921 ATH Albemarle) Solid glassspheres 3000 CP- 11.80 01 SPHERIGLASS Thickener A (PG-91146) 5.60 7.10Thickener B (AM-9033) 1.84 1.84 Glass fibers (P-973CAB-113) 115.80115.80 122.20 129.40 Total 526.74 526.74 555.40 588.38

TABLE 3 Example 9 10 11 12 Resin A (S903) 54.40 61.10 56.50 55.20 ResinC (31-615-20-X) Styrene Monomer (R-152) Resin B (Q-8000) 40.00 33.3037.70 38.80 Monomer A 5.60 5.60 5.80 6.00 (ROCRYL 400 [HEMA]) Dispersingagent A (BYK-W- 4.40 4.40 4.60 4.80 996) Flame retardant A 5.60 5.604.60 9.00 (Antiblaze DMMP) Initiator A (TRIG. BPIC-C75) 1.10 1.10 1.201.20 Initiator B (TRIG.21OP50) 0.40 0.40 0.30 0.40 Inhibitor A (IN-9073)0.20 0.20 0.20 0.20 Mold release agent 5.60 5.60 5.80 6.00 (NORAC COAD27D ZNST) Colorant A (11-81521 [Grey]) 8.30 8.70 9.00 Flame retardant B(Martinal 302.00 311.00 320.00 329.00 ON-921 ATH Albemarle) Solid glassspheres (3000 CP- 01 SPHERIGLASS) Thickener A (PG-91146) 5.60 5.60 5.806.00 Thickener B (AM-9033) Glass fibers (P-973CAB-113) 122.20 122.20127.50 131.30 Total 555.40 566.10 578.70 596.90

TABLE 4 Example 13 14 15 16 Resin D 74.30 (31009 [44314/ATLAC 490INT])Resin A S903 53.40 72.00 74.30 Resin C (31-615-20-X) Styrene monomer(R-152) Resin B (Q-8000) 35.60 16.70 17.10 17.10 Monomer A 11.00 11.108.60 8.60 (ROCRYL 400 [HEMA]) Dispersing agent A 4.00 4.40 4.60 4.60(BYK-W-996) Flame retardant A (Antiblaze DMMP) Initiator A (TRIG.BPIC-C75) 1.10 1.30 1.30 1.40 Inhibitor B (IN-91029) .60 Initiator B(TRIG.21OP50) 0.30 Inhibitor A (IN-9073) 0.20 0.20 0.20 Mold releaseagent A 5.50 5.60 5.70 5.70 (NORAC COAD 27D ZNST) Colorant (11-81521[Grey]) 8.20 8.60 8.60 Flame retardant B (Martinal 302.00 317.00 321.00320.00 ON-921 ATH Albemarle) Solid glass spheres (3000 CP- 01SPHERIGLASS) Thickener A (PG-91146) 5.50 4.40 5.10 Thickener B (AM-9033)4.60 Glass fibers (P-973CAB-113) 121.00 122.00 125.70 125.70 Total547.80 555.10 571.70 571.30

TABLE 5 Example 17 18 19 Resin E (S988-500) 45.60 Resin A (S903) 73.5076.50 45.60 Resin C (31-615-20-X) Styrene monomer (R-152) 17.70 17.70Resin B (Q-8000) Monomer A 8.80 5.80 8.80 (ROCRYL 400 [HEMA] Dispersingagent A 4.70 3.50 4.70 (BYK-W-996) Flame retardant A 11.80 11.80 11.80(Antiblaze DMMP) Initiator A (TRIG. BPIC-C75) 1.50 1.50 1.20 Inhibitor B(IN-91029) Initiator B (TRIG.21OP50) 0.50 Inhibitor A (IN-9073) 0.200.20 0.20 Mold release agent A 5.90 5.80 5.90 (NORAC COAD 27D ZNST)Colorant A (11-81521 [Grey]) 8.80 8.80 Rheological additive A 0.50(GARAMITE 1210) Flame retardant B (Martinal 321.00 326.70 327.00 ON-921ATH Albemarle) Solid glass spheres (3000 CP- 01 SPHERIGLASS) Thickener A(PG-91146) 4.70 Thickener B (AM-9033) 2.60 1.80 Glass fibers(P-973CAB-113) 129.40 129.40 129.40 Total 588.00 590.80 588.40

TABLE 6 Example 20 21 22 23 Low profile additive A (FN-510) 11.40 ResinA (S903) 71.40 91.40 Resin C (31-615-20-X) 73.50 71.40 Low profileadditive B (N-700) 17.20 Styrene monomer (R-152) Resin B (Q-8000) 17.2017.70 Monomer A 11.40 8.80 11.40 8.60 (ROCRYL 400 [HEMA] Dispersingagent A 4.60 (BYK-W-996) Flame retardant A 11.40 14.70 11.40 (AntiblazeDMMP) Initiator A (TRIG. BPIC-C750 1.10 1.20 1.10 1.10 Initiator B(IN-910290) Inhibitor B (TRIG.21OP50) 0.50 0.50 0.50 0.50 Inhibitor A(IN-9073) 0.20 0.20 0.20 0.20 Mold release agent 5.70 5.90 5.70 5.70(NORAC COAD 27D ZNST) Colorant (11-81521 [Grey]) 8.60 8.80 8.60 8.60Rheological additive A (GARAMITE 1210) Flame retardant B (Martinal315.00 325.00 315.00 310.00 ON-921 ATH Albemarle) Solid glass sphere(3000 CP- 01 SPHERIGLASS) Thickener A (PG-91146) Thickener B (AM-9033)3.40 2.90 2.90 3.10 Glass fibers (P-973CAB-113) 125.70 129.40 125.70125.70 Total 571.60 588.60 571.10 574.00

TABLE 7 Example 24 25 26 27 Resin A (S903) 52.26 52.50 52.50 52.50 ResinB (Q-8000) 34.84 35.00 35.00 35.00 Monomer A 12.90 12.50 12.50 12.50(ROCRYL 400 [HEMA]) Dispersing agent A 5.48 5.31 5.31 5.31 (BYK-W-996)Initiator A (TRIG. BPIC-C75) 1.23 1.19 1.19 1.19 Initiator B(TRIG.21OP50) 0.26 0.25 0.25 0.25 Inhibitor A (IN-9073) 0.20 1.44 1.441.44 Mold release agent A 6.45 6.25 6.25 6.25 (NORAC COAD 27D ZNST)Colorant A (11-81521 [Grey]) 9.68 9.38 9.38 9.38 Flame retardant B(Martinal 359.61 355.56 354.31 353.06 ON-921 ATH Albemarle) IONPUREwpa<50 12.90 1.88 3.12 4.38 Thickener A (PG-91146) 6.13 6.25 6.25 6.25Glass fibers (P-973CAB-113) 142.00 137.50 137.50 137.50 Total 6.45.22625.01 625.00 625.01

TABLE 8 Example 28 29 30 31 Resin F (31610) 72.56 72.56 72.56 73.72R-100 (styrene solution) 17.98 17.98 17.98 18.27 Styrene monomer 9.469.46 9.46 8.01 Low profile additive A 1.58 1.58 1.58 1.60 Initiator A(TRIG. BPIC-C75) 0.79 0.79 0.79 0.80 Initiator B (TRIG.21OP50) 0.35 0.350.35 0.35 Inhibitor A (IN-9073) 0.09 0.09 0.09 0.10 Mold release agent A3.15 3.15 3.15 3.21 (NORAC COAD 27D ZNST) IONPURE wpa<50 0.95 1.58 2.216.41 SB 222 (alumina trihydrate) 94.19 93.56 92.93 91.9 SB 432 (aluminatrihydrate) 31.55 31.55 31.55 32.05 Sb203 [antimony trioxide] 3.94 1.253.94 4.01 FR-1210 DBDPO 7.89 Thickener B (AM-9033) 1.58 1.58 1.58 1.60Glass fibers (5509 [16 micron]) 69.4 69.40 69.40 70.51 Total 315.46315.46 315.46 237.84

Flat panels of 24″ by 36″ by 0.100″ thick were molded as described aboveusing the compound of example 13. These panels were supplied to anindependent testing laboratory which tested the samples in accordancewith UL 723 Class I. The compound was found to meet the 25/50 criteria.In addition, flat panels were made using the same recipe by at thefollowing levels of Flame Retardant B, 300, 350 and 380. These sampleswere sent to Underwriters Laboratories in Chicago for testing inaccordance with UL 723.

While in accordance with the Patent Statutes, the best mode andpreferred embodiment have been set forth, the scope of the invention isnot limited thereto, but rather by the scope of the attached claims.

1. A component for an air handler or hot air furnace which is the moldedproduct of a molding composition, comprising: a) a thermoset resinsystem which includes an unsaturated polyester which is the product of acondensation polymerization between a polyol and an acid or an anhydrideand which is dissolved in a reactive monomer, and further optionallyincluding a low profile additive; b) from about 10 to about 30 percentby weight of glass fiber based upon the total weight of the compositionc) an initiator to initiate said copolymerization; d) a flame retardantcomprising aluminum hydroxide in an amount from about 45 to about 60% byweight and whereby the molding composition when molded meets thestandard of UL 723; and e) an antimicrobial agent.
 2. A component as setforth in claim 1, wherein the low profile additive is present in anamount of from about 35 to about 45% by weight of the resin system andwherein the low profile additive is a saturated polyester, and themolding composition includes a thickening agent comprising magnesiumoxide or magnesium hydroxide.
 3. A component as set forth in claim 1,wherein the antimicrobial agent includes one or more of triclosan, orsilver ions.
 4. A component as set forth in claim 3, wherein thethermoset resin comprises a copolymer of C2-C16 alkylene glycol andC5-C36 cycloalkylene compound.
 5. A component as set forth in claim 4,wherein the resin comprises propylene glycol, dicyclopentadiene andmaleic anhydride blended with a saturated polyester low profile additiveand with a hydroxyethyl methacrylate monomer.
 6. A component as setforth in claim 5, wherein the amount of glass fiber is from about 15 toabout 25 percent based upon the total weight.
 7. A component as setforth in claim 6, wherein said antimicrobial agent comprises one or moreof a soluble glass containing silver ions, silver sodium hydrogenzirconium phosphate, and silver zeolite
 8. A component as set forth inclaim 7, wherein the component is a drain pan, a base pan, a blowerhousing, a heating or air conditioner component, or a furnace housing.9. A component as set forth in claim 1, wherein flame retardant ispresent at from about 300 to about 320 parts by weight based upon theweight of the resin system.
 10. A method of making a component for anair handler, air conditioner, or hot air furnace comprising molding thehousing from a composition, comprising: a) a thermoset resin whichincludes an unsaturated polyester which is the product of a condensationpolymerization between a polyol and an acid or an anhydride and which isdissolved in a reactive monomer, and further optionally including a lowprofile additive; b) from about 10 to about 30 percent by weight ofglass fiber based upon the total weight of the composition c) aninitiator to initiate said copolymerization; d) a flame retardantcomprising aluminum hydroxide in an amount from about 45 to about 60% byweight and whereby the molding composition meets the standard of UL 723;and e) an antimicrobial agent.
 11. A method of making a component as setforth in claim 10, wherein the thermoset resin comprises a copolymer ofC2-C16 alkylene glycol and C5-C36 cycloalkylene compound.
 12. A methodof making a component as set forth in claim 11, wherein the resinincludes a C1-C12 OH functionalized acrylate monomer, dimer or trimer;the reactive monomer is one or more of styrene and tolulene and the lowprofile additive is a saturated polyester.
 13. A method of making acomponent as set forth in claim 12, wherein the resin comprisespropylene glycol, dicyclopentadiene and maleic anhydride blended with asaturated polyester low profile additive and with a hydroxyethylmethacrylate monomer.
 14. A method of making a component as set forth inclaim 10, wherein the antimicrobial agent comprises one or more oftriclosan; a soluble glass containing silver ions, silver sodiumhydrogen zirconium phosphate; and silver zeolite.
 15. A moldingcomposition, comprising: a) a thermoset resin which includes anunsaturated polyester which is the product of a condensationpolymerization between a polyol and an acid or an anhydride and which isdissolved in a reactive monomer, and further optionally including a lowprofile additive; b) from about 10 to about 30 percent by weight ofglass fiber based upon the total weight of the composition c) aninitiator to initiate said copolymerization; d) a flame retardantcomprising aluminum hydroxide in an amount from about 45 to about 60% byweight and whereby the molding composition meets the standard of UL 723and e) an antimicrobial agent comprising one or more of triclosan; asoluble glass containing silver ions, silver sodium hydrogen zirconiumphosphate; and silver zeolite
 16. A molding composition as set forth inclaim 15, wherein the resin further includes a C1-C12 OH functionalizedacrylate monomer, dimer or trimer; the reactive monomer is one or moreof styrene and tolulene; and the low profile additive is a saturatedpolyester.
 17. A molding composition as set forth in claim 16, whereinthe resin comprises propylene glycol, dicyclopentadiene and maleicanhydride blended with a saturated polyester low profile additive andwith a hydroxyethyl methacrylate monomer.
 18. A molding composition asset forth in claim 17, wherein the amount of glass fiber is from about15 to about 25 percent based upon the total weight.
 19. A moldingcomposition, comprising: a) a thermoset resin system which includes anunsaturated polyester which is the product of a condensationpolymerization between a polyol and an acid or an anhydride and which isdissolved in a reactive monomer, and a low profile additive, said lowprofile additive being about 35 to about 45% by weight of the resinsystem b) from about 10 to about 30 percent by weight of glass fiberbased upon the total weight of the composition c) an initiator toinitiate said copolymerization; d) a thickener comprising magnesiumhydroxide or magnesium oxide; e) a flame retardant comprising aluminumhydroxide in an amount from about 300 to about 380 parts per hundredbased upon the weight of the resin system; and f) an antimicrobial agentcomprising one or more of triclosan; a soluble glass containing silverions, silver sodium hydrogen zirconium phosphate; and silver zeolite 20.A composition as set forth in claim 19, wherein the thermoset resincomprises a copolymer of C2-C16 alkylene glycol and C5-C36 cycloalkylenecompound.
 21. A composition as set forth in claim 20, wherein saidreactive monomer comprises styrene and the composition is not more than10% by weight of styrene.
 22. A composition as set forth in claim 21,wherein the resin further includes a C1-C12 OH functionalized acrylatemonomer, dimer or trimer; and wherein the low profile additive is asaturated polyester.
 23. A composition as set forth in claim 22, whereinthe resin comprises propylene glycol, dicyclopentadiene and maleicanhydride blended with a saturated polyester low profile additive andwith a hydroxyethyl methacrylate monomer.
 24. A composition as set forthin claim 23, wherein the amount of glass fiber is from about 15 to about25 percent based upon the total weight.
 25. A composition as set forthin claim 24, wherein the antimicrobial agent is a soluble glasscontaining silver ions and is present in an amount from about 0.02 toabout 0.2 percent based upon the total weight of the composition.